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Inventories - Schedule of Inventory Components (Detail) (USD $)
In Millions, unless otherwise specified
Mar. 31, 2014
Dec. 31, 2013
Inventory Disclosure [Abstract]    
Finished goods $ 702 $ 578
Work-in-process 1,006 828
Bauxite and alumina 597 581
Purchased raw materials 528 474
Operating supplies 234 244
Inventories, total $ 3,067 $ 2,705