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  <xs:element id="cf_OtherComprehensiveIncomeLossDefinedBenefitPlanCurtailmentGainBeforeTax" abstract="false" name="OtherComprehensiveIncomeLossDefinedBenefitPlanCurtailmentGainBeforeTax" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_AmendmentNo.4totheThirdAmendedandRestatedRevolvingCreditAgreementMember" abstract="true" name="AmendmentNo.4totheThirdAmendedandRestatedRevolvingCreditAgreementMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
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  <xs:element id="cf_AcquisitionOfTreasuryStockUnderEmployeeStockPlans" abstract="false" name="AcquisitionOfTreasuryStockUnderEmployeeStockPlans" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_AssetRetirementObligationsLiabilityNotRecognizedEstimatedAmount" abstract="false" name="AssetRetirementObligationsLiabilityNotRecognizedEstimatedAmount" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_DefinedBenefitPlanAccrualsAndPayablesNetMember" abstract="true" name="DefinedBenefitPlanAccrualsAndPayablesNetMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
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  <xs:element id="cf_EffectiveIncomeTaxRateReconciliationTransferPricingArbitrationAmount" abstract="false" name="EffectiveIncomeTaxRateReconciliationTransferPricingArbitrationAmount" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_UnitedKingdomTerraMember" abstract="true" name="UnitedKingdomTerraMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="cf_DefinedBenefitPlanAssumptionsUsedinCalculationWeightedAverageInterestCreditingRate" abstract="false" name="DefinedBenefitPlanAssumptionsUsedinCalculationWeightedAverageInterestCreditingRate" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="cf_CapitalizedPlantTurnaroundCostChangesInExchangeRateEffect" abstract="false" name="CapitalizedPlantTurnaroundCostChangesInExchangeRateEffect" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_SharebasedCompensationArrangementbySharebasedPaymentAwardEquityInstrumentsOtherthanOptionsWeightedAverageExercisePriceRollForwardRollForward" abstract="true" name="SharebasedCompensationArrangementbySharebasedPaymentAwardEquityInstrumentsOtherthanOptionsWeightedAverageExercisePriceRollForwardRollForward" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
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  <xs:element id="cf_FixedIncomePooledUKGovernmentIndexLinkedSecuritiesMember" abstract="true" name="FixedIncomePooledUKGovernmentIndexLinkedSecuritiesMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="cf_DefinedBenefitPlanPlanAssetsAmountPriorToRedemption" abstract="false" name="DefinedBenefitPlanPlanAssetsAmountPriorToRedemption" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_ReconciliationofDepreciationDepletionandAmortizationfromSegmenttoConsolidatedTableTextBlock" abstract="false" name="ReconciliationofDepreciationDepletionandAmortizationfromSegmenttoConsolidatedTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
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  <xs:element id="cf_CashEquivalentsatFairValue" abstract="false" name="CashEquivalentsatFairValue" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_DefinedBenefitPlanNetPeriodicBenefitCostCreditSettlementGainLossStatementOfIncomeOrComprehensiveIncomeExtensibleListNotDisclosedFlag" abstract="false" name="DefinedBenefitPlanNetPeriodicBenefitCostCreditSettlementGainLossStatementOfIncomeOrComprehensiveIncomeExtensibleListNotDisclosedFlag" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
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  <xs:element id="cf_IncomeTaxExaminationLiabilityRefundAdjustmentFromSettlementWithTaxingAuthorityIncomeTaxMatter" abstract="false" name="IncomeTaxExaminationLiabilityRefundAdjustmentFromSettlementWithTaxingAuthorityIncomeTaxMatter" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_EffectiveIncomeTaxRateReconciliationBasisDifferenceInForeignPartnershipAmount" abstract="false" name="EffectiveIncomeTaxRateReconciliationBasisDifferenceInForeignPartnershipAmount" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_DefinedBenefitPlanNumberOfFundedPlans" abstract="false" name="DefinedBenefitPlanNumberOfFundedPlans" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="cf_ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsExercisesInPeriodTableTextBlock" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsExercisesInPeriodTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
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  <xs:element id="cf_RevenueRemainingPerformanceObligationExpectedTimingofSatisfactionPercent" abstract="false" name="RevenueRemainingPerformanceObligationExpectedTimingofSatisfactionPercent" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:percentItemType"/>
  <xs:element id="cf_PooledTargetReturnFundsMember" abstract="true" name="PooledTargetReturnFundsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
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  <xs:element id="cf_Deferredtaxliabilitiesoperatingleaserightofuseassets" abstract="false" name="Deferredtaxliabilitiesoperatingleaserightofuseassets" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_EmployeeServiceShareBasedCompensationTaxBenefitRealizedFromVestingOfEquityInstrumentsOtherThanOptions" abstract="false" name="EmployeeServiceShareBasedCompensationTaxBenefitRealizedFromVestingOfEquityInstrumentsOtherThanOptions" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_NoncontrollingInterestDeferredTaxAssetRelatedToNoncontrollingInterest" abstract="false" name="NoncontrollingInterestDeferredTaxAssetRelatedToNoncontrollingInterest" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_DefinedBenefitPlanChangeInAssumptionsAndOther" abstract="false" name="DefinedBenefitPlanChangeInAssumptionsAndOther" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_DeferredTaxAssetsOtherNetOperatingLossCarryforwards" abstract="false" name="DeferredTaxAssetsOtherNetOperatingLossCarryforwards" nillable="true" xbrli:periodType="instant" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_ContractwithCustomerPaymentPeriod" abstract="false" name="ContractwithCustomerPaymentPeriod" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="cf_CapitalizedPlantTurnAroundCostsTableTextBlock" abstract="false" name="CapitalizedPlantTurnAroundCostsTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="cf_PensionAndOtherPostretirementDefinedBenefitPlansAndDeferredCompensationLiabilitiesNoncurrent" abstract="false" name="PensionAndOtherPostretirementDefinedBenefitPlansAndDeferredCompensationLiabilitiesNoncurrent" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_NumberofNitrogenFertilizerManufacturingFacilitiesNorthAmerica" abstract="false" name="NumberofNitrogenFertilizerManufacturingFacilitiesNorthAmerica" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="cf_OtherSundryOperatingCostAndExpense" abstract="false" name="OtherSundryOperatingCostAndExpense" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_MaximumAnnualUANTonsEligibleforPurchase" abstract="false" name="MaximumAnnualUANTonsEligibleforPurchase" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:weightItemType"/>
  <xs:element id="cf_RestrictedStockUnitsAndRestrictedStockAwardsMember" abstract="true" name="RestrictedStockUnitsAndRestrictedStockAwardsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="cf_TerraCanadianPlanMember" abstract="true" name="TerraCanadianPlanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="cf_InterestOnTaxLiabilities" abstract="false" name="InterestOnTaxLiabilities" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="cf_PlantTurnaroundCostsDisclosureAbstract" abstract="true" name="PlantTurnaroundCostsDisclosureAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
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  <xs:element id="cf_FeeOnFinancingAgreementsAmount" abstract="false" name="FeeOnFinancingAgreementsAmount" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_EquityInEarningsOfOperatingAffiliates" abstract="false" name="EquityInEarningsOfOperatingAffiliates" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_MinorityInterestDistributionsToNoncontrollingInterestHolders" abstract="false" name="MinorityInterestDistributionsToNoncontrollingInterestHolders" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_ExcessTaxBenefitFromShareBasedCompensation" abstract="false" name="ExcessTaxBenefitFromShareBasedCompensation" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
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  <xs:element id="cf_MaximumAnnualGranularUreaTonsEligibleforPurchase" abstract="false" name="MaximumAnnualGranularUreaTonsEligibleforPurchase" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:weightItemType"/>
  <xs:element id="cf_DefinedBenefitPlanReceivablesNetMember" abstract="true" name="DefinedBenefitPlanReceivablesNetMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="cf_RawMaterialAndSparePartsMember" abstract="true" name="RawMaterialAndSparePartsMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
</xs:schema>
