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Business Segments (Details) (USD $) In Millions, unless otherwise specified | 3 Months Ended | 12 Months Ended
--- | --- | ---
Dec. 31, 2013 | Sep. 30, 2013 | Jun. 30, 2013 | Mar. 31, 2013 | Dec. 31, 2012 | Sep. 30, 2012 | Jun. 30, 2012 | Mar. 31, 2012 | Dec. 31, 2013 segment | Dec. 31, 2012 | Dec. 31, 2011
Segment Reporting [Abstract] |  |  |  |  |  |  |  |  |  |  |
Number of reportable segments |  |  |  |  |  |  |  |  | 2 |  |
Business Segments |  |  |  |  |  |  |  |  |  |  |
Net sales | $ 2,436.0 | $ 1,977.1 | $ 2,220.3 | $ 2,352.4 | $ 1,880.8 | $ 2,409.6 | $ 2,308.3 | $ 1,968.6 | $ 8,985.8 | $ 8,567.3 | $ 5,029.1
Cost of product sold (exclusive of depreciation and amortization) | 2,219.7 | 1,744.4 | 1,785.4 | 1,813.6 | 1,485.1 | 1,702.5 | 1,874.2 | 1,635.2 | 7,563.2 | 6,696.9 | 3,943.5
Direct operating expenses (exclusive of depreciation and amortization) | 110.6 | 128.4 | 108.3 | 108.5 | 202.5 | 109.9 | 94.1 | 115.5 | 455.8 | 522.1 | 334.1
Depreciation and amortization | 37.4 | 36.2 | 35.0 | 34.2 | 32.6 | 33.1 | 32.2 | 32.1 | 142.8 | 130.0 | 90.3
Operating income | 39.7 | 40.4 | 262.7 | 367.7 | 124.9 | 533.7 | 235.8 | 140.5 | 710.5 | 1,034.9 | 566.6
Capital expenditures |  |  |  |  |  |  |  |  | 256.5 | 212.2 | 91.2
Total assets | 3,665.8 |  |  |  | 3,610.9 |  |  |  | 3,665.8 | 3,610.9 | 3,119.3
Goodwill | 41.0 |  |  |  | 41.0 |  |  |  | 41.0 | 41.0 | 41.0
Petroleum |  |  |  |  |  |  |  |  |  |  |
Business Segments |  |  |  |  |  |  |  |  |  |  |
Intercompany sales |  |  |  |  |  |  |  |  | 9.6 | 9.9 | 11.4
Intercompany cost of product sold (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 11.4 | 6.1 | 13.2
Net sales |  |  |  |  |  |  |  |  | 8,683.5 | 8,281.5 | 4,751.8
Cost of product sold (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 7,526.7 | 6,667.3 | 3,926.6
Direct operating expenses (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 361.7 | 426.5 | 247.7
Depreciation and amortization |  |  |  |  |  |  |  |  | 114.3 | 107.6 | 69.9
Operating income |  |  |  |  |  |  |  |  | 603.0 | 1,012.5 | 465.7
Capital expenditures |  |  |  |  |  |  |  |  | 204.5 | 120.0 | 68.6
Total assets | 2,533.3 |  |  |  | 2,258.5 |  |  |  | 2,533.3 | 2,258.5 | 2,322.1
Goodwill | 0 |  |  |  | 0 |  |  |  | 0 | 0 | 0
Petroleum | Hydrogen |  |  |  |  |  |  |  |  |  |  |
Business Segments |  |  |  |  |  |  |  |  |  |  |
Intercompany sales |  |  |  |  |  |  |  |  | 0.6 |  |
Nitrogen Fertilizer |  |  |  |  |  |  |  |  |  |  |
Business Segments |  |  |  |  |  |  |  |  |  |  |
Intercompany sales |  |  |  |  |  |  |  |  | 11.4 | 6.3 | 14.2
Intercompany cost of product sold (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 9.8 | 10.2 | 10.7
Cost of product sold related to the transfer of excess hydrogen |  |  |  |  |  |  |  |  | 0.6 | 0.2 | 1.0
Net sales |  |  |  |  |  |  |  |  | 323.7 | 302.3 | 302.9
Cost of product sold (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 58.1 | 46.1 | 42.5
Direct operating expenses (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 94.1 | 95.6 | 86.5
Depreciation and amortization |  |  |  |  |  |  |  |  | 25.6 | 20.7 | 18.9
Operating income |  |  |  |  |  |  |  |  | 124.9 | 115.8 | 136.2
Capital expenditures |  |  |  |  |  |  |  |  | 43.8 | 82.2 | 19.1
Total assets | 593.5 |  |  |  | 623.0 |  |  |  | 593.5 | 623.0 | 659.3
Goodwill | 41.0 |  |  |  | 41.0 |  |  |  | 41.0 | 41.0 | 41.0
Other |  |  |  |  |  |  |  |  |  |  |
Business Segments |  |  |  |  |  |  |  |  |  |  |
Direct operating expenses (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | 0 | 0 | (0.1)
Depreciation and amortization |  |  |  |  |  |  |  |  | 2.9 | 1.7 | 1.5
Operating income |  |  |  |  |  |  |  |  | (17.4) | (93.4) | (35.3)
Capital expenditures |  |  |  |  |  |  |  |  | 8.2 | 10.0 | 3.5
Total assets | 539.0 |  |  |  | 729.4 |  |  |  | 539.0 | 729.4 | 137.9
Goodwill | 0 |  |  |  | 0 |  |  |  | 0 | 0 | 0
Intersegment elimination |  |  |  |  |  |  |  |  |  |  |
Business Segments |  |  |  |  |  |  |  |  |  |  |
Net sales |  |  |  |  |  |  |  |  | (21.4) | (16.5) | (25.6)
Cost of product sold (exclusive of depreciation and amortization) |  |  |  |  |  |  |  |  | $ (21.6) | $ (16.5) | $ (25.6)

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