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Business Segments (Details 1)
$ in Millions
3 Months Ended 12 Months Ended
Dec. 31, 2016
USD ($)
Sep. 30, 2016
USD ($)
Jun. 30, 2016
USD ($)
Mar. 31, 2016
USD ($)
Dec. 31, 2015
USD ($)
Sep. 30, 2015
USD ($)
Jun. 30, 2015
USD ($)
Mar. 31, 2015
USD ($)
Dec. 31, 2016
USD ($)
segment
Dec. 31, 2015
USD ($)
Dec. 31, 2014
USD ($)
Segment Reporting Information [Line Items]                      
Number of reportable segments | segment                 2    
Net sales $ 1,353.4 $ 1,240.3 $ 1,283.2 $ 905.5 $ 1,010.6 $ 1,408.8 $ 1,624.2 $ 1,388.9 $ 4,782.4 $ 5,432.5 $ 9,109.5
Cost of materials and other $ 1,128.1 $ 1,005.7 $ 976.9 $ 736.8 $ 847.9 $ 1,076.7 $ 1,192.2 $ 1,073.6 3,847.5 4,190.4 8,066.0
Intersegment elimination                      
Segment Reporting Information [Line Items]                      
Net sales                 (5.2) (18.6) (18.9)
Cost of materials and other                 (5.4) (18.4) (19.4)
Intersegment elimination | Petroleum                      
Segment Reporting Information [Line Items]                      
Net sales                 1.8 6.8 8.7
Cost of materials and other                 3.2 11.8 10.1
Intersegment elimination | Nitrogen Fertilizer                      
Segment Reporting Information [Line Items]                      
Net sales                 3.0 11.8 10.1
Cost of materials and other                 2.1 $ 6.6 $ 9.2
Intersegment elimination | Hydrogen | Petroleum                      
Segment Reporting Information [Line Items]                      
Net sales                 $ 0.2