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Business Segments (Details 2) - USD ($)
$ in Millions
3 Months Ended 12 Months Ended
Dec. 31, 2016
Sep. 30, 2016
Jun. 30, 2016
Mar. 31, 2016
Dec. 31, 2015
Sep. 30, 2015
Jun. 30, 2015
Mar. 31, 2015
Dec. 31, 2016
Dec. 31, 2015
Dec. 31, 2014
Segment Reporting Information [Line Items]                      
Net sales $ 1,353.4 $ 1,240.3 $ 1,283.2 $ 905.5 $ 1,010.6 $ 1,408.8 $ 1,624.2 $ 1,388.9 $ 4,782.4 $ 5,432.5 $ 9,109.5
Cost of materials and other 1,128.1 1,005.7 976.9 736.8 847.9 1,076.7 1,192.2 1,073.6 3,847.5 4,190.4 8,066.0
Direct operating expenses (exclusive of depreciation and amortization as reflected below) 132.6 129.5 138.3 141.4 212.1 145.8 115.4 111.4 541.8 584.7 515.1
Depreciation and amortization                 193.1 164.1 154.4
Operating income 12.9 $ 27.2 $ 90.7 $ (39.9) (110.7) $ 121.5 $ 274.2 $ 136.6 90.9 421.6 264.3
Capital expenditures                 132.7 218.7 218.4
Total assets 4,050.2       3,299.4       4,050.2 3,299.4 3,454.3
Goodwill of VIEs 41.0       41.0       41.0 41.0 41.0
Operating Segments | Petroleum                      
Segment Reporting Information [Line Items]                      
Net sales                 4,431.3 5,161.9 8,829.7
Cost of materials and other                 3,759.2 4,143.6 8,013.4
Direct operating expenses (exclusive of depreciation and amortization as reflected below)                 393.4 478.5 416.0
Operating income                 77.8 361.7 207.2
Capital expenditures                 102.3 194.7 191.3
Total assets 2,331.9       2,189.0       2,331.9 2,189.0 2,410.7
Goodwill of VIEs 0.0       0.0       0.0 0.0 0.0
Operating Segments | Nitrogen Fertilizer                      
Segment Reporting Information [Line Items]                      
Net sales                 356.3 289.2 298.7
Cost of materials and other                 93.7 65.2 72.0
Direct operating expenses (exclusive of depreciation and amortization as reflected below)                 148.3 106.1 98.9
Depreciation and amortization                 58.2 28.4 27.3
Operating income                 26.8 68.7 82.8
Capital expenditures                 23.2 17.0 21.1
Total assets 1,312.2       536.3       1,312.2 536.3 577.8
Goodwill of VIEs 41.0       41.0       41.0 41.0 41.0
Intersegment elimination                      
Segment Reporting Information [Line Items]                      
Net sales                 (5.2) (18.6) (18.9)
Cost of materials and other                 (5.4) (18.4) (19.4)
Intersegment elimination | Petroleum                      
Segment Reporting Information [Line Items]                      
Net sales                 1.8 6.8 8.7
Cost of materials and other                 3.2 11.8 10.1
Intersegment elimination | Nitrogen Fertilizer                      
Segment Reporting Information [Line Items]                      
Net sales                 3.0 11.8 10.1
Cost of materials and other                 2.1 6.6 9.2
Other                      
Segment Reporting Information [Line Items]                      
Direct operating expenses (exclusive of depreciation and amortization as reflected below)                 0.1 0.1 0.2
Depreciation and amortization                 5.9 5.5 4.6
Operating income                 (13.7) (8.8) (25.7)
Capital expenditures                 7.2 7.0 6.0
Total assets 406.1       574.1       406.1 574.1 465.8
Goodwill of VIEs $ 0.0       $ 0.0       $ 0.0 $ 0.0 $ 0.0