<?xml version="1.0" encoding="US-ASCII" standalone="no"?>
    <!-- Field: Doc-Info; Name: Generator; Value: GoFiler Complete; Version: 5.18b -->
    <!-- Field: Doc-Info; Name: VendorURI; Value: https://www.novaworks.com -->
    <!-- Field: Doc-Info; Name: Status; Value: 0x00000000 -->
<link:linkbase xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xbrldt="http://xbrl.org/2005/xbrldt" xmlns:xbrli="http://www.xbrl.org/2003/instance" xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd">
    <link:roleRef roleURI="http://premiumnickelresources.com/role/Cover" xlink:href="pnrl-20230331.xsd#Cover" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfFinancialPosition" xlink:href="pnrl-20230331.xsd#InterimConsolidatedStatementsOfFinancialPosition" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfComprehensiveLoss" xlink:href="pnrl-20230331.xsd#InterimConsolidatedStatementsOfComprehensiveLoss" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfChangesInShareholdersEquity" xlink:href="pnrl-20230331.xsd#InterimConsolidatedStatementsOfChangesInShareholdersEquity" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfChangesInShareholdersEquityParenthetical" xlink:href="pnrl-20230331.xsd#InterimConsolidatedStatementsOfChangesInShareholdersEquityParenthetical" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfCashFlows" xlink:href="pnrl-20230331.xsd#InterimConsolidatedStatementsOfCashFlows" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/NatureOfOperationsAndGoingConcern" xlink:href="pnrl-20230331.xsd#NatureOfOperationsAndGoingConcern" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/BasisOfPreparationAndSignificantAccountingPolicies" xlink:href="pnrl-20230331.xsd#BasisOfPreparationAndSignificantAccountingPolicies" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/Amalgamation" xlink:href="pnrl-20230331.xsd#Amalgamation" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/OtherReceivables" xlink:href="pnrl-20230331.xsd#OtherReceivables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ExplorationAndEvaluationAssets" xlink:href="pnrl-20230331.xsd#ExplorationAndEvaluationAssets" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/PropertyPlantAndEquipment" xlink:href="pnrl-20230331.xsd#PropertyPlantAndEquipment" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/TradePayablesAndAccruedLiabilities" xlink:href="pnrl-20230331.xsd#TradePayablesAndAccruedLiabilities" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/PromissoryNote" xlink:href="pnrl-20230331.xsd#PromissoryNote" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/LeaseLiability" xlink:href="pnrl-20230331.xsd#LeaseLiability" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ShareCapitalWarrantsAndOptions" xlink:href="pnrl-20230331.xsd#ShareCapitalWarrantsAndOptions" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/RelatedPartyTransactions" xlink:href="pnrl-20230331.xsd#RelatedPartyTransactions" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/FinancialInstruments" xlink:href="pnrl-20230331.xsd#FinancialInstruments" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/RiskManagement" xlink:href="pnrl-20230331.xsd#RiskManagement" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SegmentedInformation" xlink:href="pnrl-20230331.xsd#SegmentedInformation" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ContingentLiabilities" xlink:href="pnrl-20230331.xsd#ContingentLiabilities" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SubsequentEvents" xlink:href="pnrl-20230331.xsd#SubsequentEvents" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/BasisOfPreparationAndSignificantAccountingPoliciesPolicies" xlink:href="pnrl-20230331.xsd#BasisOfPreparationAndSignificantAccountingPoliciesPolicies" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/AmalgamationTables" xlink:href="pnrl-20230331.xsd#AmalgamationTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/OtherReceivablesTables" xlink:href="pnrl-20230331.xsd#OtherReceivablesTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ExplorationAndEvaluationAssetsTables" xlink:href="pnrl-20230331.xsd#ExplorationAndEvaluationAssetsTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/PropertyPlantAndEquipmentTables" xlink:href="pnrl-20230331.xsd#PropertyPlantAndEquipmentTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/TradePayablesAndAccruedLiabilitiesTables" xlink:href="pnrl-20230331.xsd#TradePayablesAndAccruedLiabilitiesTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/PromissoryNoteTables" xlink:href="pnrl-20230331.xsd#PromissoryNoteTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/LeaseLiabilityTables" xlink:href="pnrl-20230331.xsd#LeaseLiabilityTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ShareCapitalWarrantsAndOptionsTables" xlink:href="pnrl-20230331.xsd#ShareCapitalWarrantsAndOptionsTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/RelatedPartyTransactionsTables" xlink:href="pnrl-20230331.xsd#RelatedPartyTransactionsTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/RiskManagementTables" xlink:href="pnrl-20230331.xsd#RiskManagementTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SegmentedInformationTables" xlink:href="pnrl-20230331.xsd#SegmentedInformationTables" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/NatureOfOperationsAndGoingConcernDetailsNarrative" xlink:href="pnrl-20230331.xsd#NatureOfOperationsAndGoingConcernDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/BasisOfPreparationAndSignificantAccountingPoliciesDetailsNarrative" xlink:href="pnrl-20230331.xsd#BasisOfPreparationAndSignificantAccountingPoliciesDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SummaryOfCostOfAcquisitionDetails" xlink:href="pnrl-20230331.xsd#SummaryOfCostOfAcquisitionDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SummaryOfCostOfAcquisitionDetailsParenthetical" xlink:href="pnrl-20230331.xsd#SummaryOfCostOfAcquisitionDetailsParenthetical" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfFairValueAssumptionsOfOptionsAndWarrantsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfFairValueAssumptionsOfOptionsAndWarrantsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/AmalgamationDetailsNarrative" xlink:href="pnrl-20230331.xsd#AmalgamationDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfReceivablesAndOtherCurrentAssetsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfReceivablesAndOtherCurrentAssetsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SummaryOfExplorationAndEvaluationAssetsDetails" xlink:href="pnrl-20230331.xsd#SummaryOfExplorationAndEvaluationAssetsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ExplorationAndEvaluationAssetsDetailsNarrative" xlink:href="pnrl-20230331.xsd#ExplorationAndEvaluationAssetsDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SummaryOfPropertyPlantAndEquipmentDetails" xlink:href="pnrl-20230331.xsd#SummaryOfPropertyPlantAndEquipmentDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SummaryOfTradePayablesAndAccruedLiabilitiesDetails" xlink:href="pnrl-20230331.xsd#SummaryOfTradePayablesAndAccruedLiabilitiesDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfFairValueOfLenderWarrantsAssumptionsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfFairValueOfLenderWarrantsAssumptionsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/PromissoryNoteDetailsNarrative" xlink:href="pnrl-20230331.xsd#PromissoryNoteDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfDetailsOfLeaseLiabilitiesDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfDetailsOfLeaseLiabilitiesDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/LeaseLiabilityDetailsNarrative" xlink:href="pnrl-20230331.xsd#LeaseLiabilityDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfOfFairValueOfBrokerWarrantsAssumptionsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfOfFairValueOfBrokerWarrantsAssumptionsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfWarrantActivityDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfWarrantActivityDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfNumberAndWeightedAverageRemainingContractualLifeOfOutstandingWarrantsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfNumberAndWeightedAverageRemainingContractualLifeOfOutstandingWarrantsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfNumberAndWeightedAverageRemainingContractualLifeOfOutstandingWarrantsDetailsParenthetical" xlink:href="pnrl-20230331.xsd#ScheduleOfNumberAndWeightedAverageRemainingContractualLifeOfOutstandingWarrantsDetailsParenthetical" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfDeferredShareUnitPlanHaveBeenGrantedDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfDeferredShareUnitPlanHaveBeenGrantedDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ShareCapitalWarrantsAndOptionsDetailsNarrative" xlink:href="pnrl-20230331.xsd#ShareCapitalWarrantsAndOptionsDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfAmountsDueToRelatedPartiesIncludedInTradePayablesAndAccruedLiabilitiesDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfAmountsDueToRelatedPartiesIncludedInTradePayablesAndAccruedLiabilitiesDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfKeyManagementCompensationDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfKeyManagementCompensationDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/RelatedPartyTransactionsDetailsNarrative" xlink:href="pnrl-20230331.xsd#RelatedPartyTransactionsDetailsNarrative" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfForeignCurrencyFinancialAssetsAndLiabilitiesDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfForeignCurrencyFinancialAssetsAndLiabilitiesDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfChangesInExchangeRatesDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfChangesInExchangeRatesDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfContractualObligationsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfContractualObligationsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfComponentsOfEquityDeficiencyLoansAndBorrowingOtherCurrentLiabilitiesNetOfCashDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfComponentsOfEquityDeficiencyLoansAndBorrowingOtherCurrentLiabilitiesNetOfCashDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/ScheduleOfGeographicSegmentsDetails" xlink:href="pnrl-20230331.xsd#ScheduleOfGeographicSegmentsDetails" xlink:type="simple" />
    <link:roleRef roleURI="http://premiumnickelresources.com/role/SubsequentEventsDetailsNarrative" xlink:href="pnrl-20230331.xsd#SubsequentEventsDetailsNarrative" xlink:type="simple" />
    <link:arcroleRef xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#hypercube-dimension" arcroleURI="http://xbrl.org/int/dim/arcrole/hypercube-dimension" />
    <link:arcroleRef xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#dimension-domain" arcroleURI="http://xbrl.org/int/dim/arcrole/dimension-domain" />
    <link:arcroleRef xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#domain-member" arcroleURI="http://xbrl.org/int/dim/arcrole/domain-member" />
    <link:arcroleRef xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#all" arcroleURI="http://xbrl.org/int/dim/arcrole/all" />
    <link:arcroleRef xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#notAll" arcroleURI="http://xbrl.org/int/dim/arcrole/notAll" />
    <link:arcroleRef xlink:type="simple" xlink:href="http://www.xbrl.org/2005/xbrldt-2005.xsd#dimension-default" arcroleURI="http://xbrl.org/int/dim/arcrole/dimension-default" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/Cover" xlink:title="00000001 - Document - Cover" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfFinancialPosition" xlink:title="00000002 - Statement - Condensed Interim Consolidated Statements of Financial Position (Unaudited)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfComprehensiveLoss" xlink:title="00000003 - Statement - Condensed Interim Consolidated Statements of Comprehensive Loss (Unaudited)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfChangesInShareholdersEquity" xlink:title="00000004 - Statement - Condensed Interim Consolidated Statements of Changes in Shareholders&apos; Equity (Unaudited)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_StatementOfChangesInEquityTable" xlink:label="loc_ifrs-fullStatementOfChangesInEquityTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_OrdinarySharesMember" xlink:label="loc_ifrs-fullOrdinarySharesMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_ifrs-fullOrdinarySharesMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PreferenceSharesMember" xlink:label="loc_ifrs-fullPreferenceSharesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_ifrs-fullPreferenceSharesMember_10" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ReserveMember" xlink:label="loc_PNRLReserveMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLReserveMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_RetainedEarningsMember" xlink:label="loc_ifrs-fullRetainedEarningsMember_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_ifrs-fullRetainedEarningsMember_30" xlink:type="arc" order="31" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ForeignCurrencyTranslationReserveMember" xlink:label="loc_PNRLForeignCurrencyTranslationReserveMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLForeignCurrencyTranslationReserveMember_40" xlink:type="arc" order="41" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_Equity" xlink:label="loc_ifrs-fullEquity_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullEquity_70" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfSharesOutstanding" xlink:label="loc_ifrs-fullNumberOfSharesOutstanding_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfSharesOutstanding_70" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ProfitLoss" xlink:label="loc_ifrs-fullProfitLoss_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullProfitLoss_70" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfShareCapitalIssuedThroughPrivatePlacementValue" xlink:label="loc_PNRLNumberOfShareCapitalIssuedThroughPrivatePlacementValue_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfShareCapitalIssuedThroughPrivatePlacementValue_70" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfShareCapitalIssuedThroughPrivatePlacementShares" xlink:label="loc_PNRLNumberOfShareCapitalIssuedThroughPrivatePlacementShares_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfShareCapitalIssuedThroughPrivatePlacementShares_70" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ShareIssueRelatedCost" xlink:label="loc_ifrs-fullShareIssueRelatedCost_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullShareIssueRelatedCost_70" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ExpenseFromSharebasedPaymentTransactionsWithEmployees" xlink:label="loc_ifrs-fullExpenseFromSharebasedPaymentTransactionsWithEmployees_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullExpenseFromSharebasedPaymentTransactionsWithEmployees_70" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_OtherComprehensiveIncomeNetOfTaxExchangeDifferencesOnTranslationOtherThanTranslationOfForeignOperations" xlink:label="loc_ifrs-fullOtherComprehensiveIncomeNetOfTaxExchangeDifferencesOnTranslationOtherThanTranslationOfForeignOperations_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullOtherComprehensiveIncomeNetOfTaxExchangeDifferencesOnTranslationOtherThanTranslationOfForeignOperations_70" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseDecreaseThroughBrokerWarrants" xlink:label="loc_PNRLIncreaseDecreaseThroughBrokerWarrants_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseDecreaseThroughBrokerWarrants_70" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseDecreaseThroughLenderWarrants" xlink:label="loc_PNRLIncreaseDecreaseThroughLenderWarrants_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseDecreaseThroughLenderWarrants_70" xlink:type="arc" order="10" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfChangesInShareholdersEquityParenthetical" xlink:title="00000005 - Statement - Condensed Interim Consolidated Statements of Changes in Shareholders&apos; Equity (Unaudited) (Parenthetical)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/InterimConsolidatedStatementsOfCashFlows" xlink:title="00000006 - Statement - Condensed Interim Consolidated Statements of Cash Flows (Unaudited)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/NatureOfOperationsAndGoingConcern" xlink:title="00000007 - Disclosure - NATURE OF OPERATIONS AND GOING CONCERN" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/BasisOfPreparationAndSignificantAccountingPolicies" xlink:title="00000008 - Disclosure - BASIS OF PREPARATION AND SIGNIFICANT ACCOUNTING POLICIES" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/Amalgamation" xlink:title="00000009 - Disclosure - AMALGAMATION" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/OtherReceivables" xlink:title="00000010 - Disclosure - OTHER RECEIVABLES" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ExplorationAndEvaluationAssets" xlink:title="00000011 - Disclosure - EXPLORATION AND EVALUATION ASSETS" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/PropertyPlantAndEquipment" xlink:title="00000012 - Disclosure - PROPERTY, PLANT AND EQUIPMENT" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/TradePayablesAndAccruedLiabilities" xlink:title="00000013 - Disclosure - TRADE PAYABLES AND ACCRUED LIABILITIES" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/PromissoryNote" xlink:title="00000014 - Disclosure - PROMISSORY NOTE" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/LeaseLiability" xlink:title="00000015 - Disclosure - LEASE LIABILITY" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ShareCapitalWarrantsAndOptions" xlink:title="00000016 - Disclosure - SHARE CAPITAL, WARRANTS AND OPTIONS" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/RelatedPartyTransactions" xlink:title="00000017 - Disclosure - RELATED PARTY TRANSACTIONS" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/FinancialInstruments" xlink:title="00000018 - Disclosure - FINANCIAL INSTRUMENTS" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/RiskManagement" xlink:title="00000019 - Disclosure - RISK MANAGEMENT" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SegmentedInformation" xlink:title="00000020 - Disclosure - SEGMENTED INFORMATION" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ContingentLiabilities" xlink:title="00000021 - Disclosure - CONTINGENT LIABILITIES" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SubsequentEvents" xlink:title="00000022 - Disclosure - SUBSEQUENT EVENTS" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/BasisOfPreparationAndSignificantAccountingPoliciesPolicies" xlink:title="00000023 - Disclosure - BASIS OF PREPARATION AND SIGNIFICANT ACCOUNTING POLICIES (Policies)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/AmalgamationTables" xlink:title="00000024 - Disclosure - AMALGAMATION (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/OtherReceivablesTables" xlink:title="00000025 - Disclosure - OTHER RECEIVABLES (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ExplorationAndEvaluationAssetsTables" xlink:title="00000026 - Disclosure - EXPLORATION AND EVALUATION ASSETS (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/PropertyPlantAndEquipmentTables" xlink:title="00000027 - Disclosure - PROPERTY, PLANT AND EQUIPMENT (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/TradePayablesAndAccruedLiabilitiesTables" xlink:title="00000028 - Disclosure - TRADE PAYABLES AND ACCRUED LIABILITIES (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/PromissoryNoteTables" xlink:title="00000029 - Disclosure - PROMISSORY NOTE (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/LeaseLiabilityTables" xlink:title="00000030 - Disclosure - LEASE LIABILITY (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ShareCapitalWarrantsAndOptionsTables" xlink:title="00000031 - Disclosure - SHARE CAPITAL, WARRANTS AND OPTIONS (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/RelatedPartyTransactionsTables" xlink:title="00000032 - Disclosure - RELATED PARTY TRANSACTIONS (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/RiskManagementTables" xlink:title="00000033 - Disclosure - RISK MANAGEMENT (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SegmentedInformationTables" xlink:title="00000034 - Disclosure - SEGMENTED INFORMATION (Tables)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/NatureOfOperationsAndGoingConcernDetailsNarrative" xlink:title="00000035 - Disclosure - NATURE OF OPERATIONS AND GOING CONCERN (Details Narrative)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/BasisOfPreparationAndSignificantAccountingPoliciesDetailsNarrative" xlink:title="00000036 - Disclosure - BASIS OF PREPARATION AND SIGNIFICANT ACCOUNTING POLICIES (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ReserveQuantitiesLineItems" xlink:label="loc_srtReserveQuantitiesLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:label="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_LegalEntityAxis" xlink:label="loc_deiLegalEntityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:to="loc_deiLegalEntityAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_deiEntityDomain" xlink:to="loc_PNRLNorthAmericanNickelIncMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PercentageOfVotingEquityInterestsAcquired" xlink:label="loc_ifrs-fullPercentageOfVotingEquityInterestsAcquired_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_ifrs-fullPercentageOfVotingEquityInterestsAcquired_20" xlink:type="arc" order="0" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SummaryOfCostOfAcquisitionDetails" xlink:title="00000037 - Disclosure - SUMMARY OF COST OF ACQUISITION (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:label="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLNorthAmericanNickelIncMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfShareTransferred" xlink:label="loc_PNRLFairValueOfShareTransferred_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFairValueOfShareTransferred_20" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfOptionsWarrantsAndAgentWarrants" xlink:label="loc_PNRLFairValueOfOptionsWarrantsAndAgentWarrants_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFairValueOfOptionsWarrantsAndAgentWarrants_20" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfPreferredShares" xlink:label="loc_PNRLFairValueOfPreferredShares_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFairValueOfPreferredShares_20" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SettlementOfPreexistingRelationship" xlink:label="loc_PNRLSettlementOfPreexistingRelationship_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLSettlementOfPreexistingRelationship_20" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_AcquisitiondateFairValueOfTotalConsiderationTransferred" xlink:label="loc_ifrs-fullAcquisitiondateFairValueOfTotalConsiderationTransferred_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullAcquisitiondateFairValueOfTotalConsiderationTransferred_20" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CashTransferred" xlink:label="loc_ifrs-fullCashTransferred_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullCashTransferred_20" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_FairValueOfAcquiredReceivables" xlink:label="loc_ifrs-fullFairValueOfAcquiredReceivables_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullFairValueOfAcquiredReceivables_20" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PropertyPlantAndEquipmentRecognisedAsOfAcquisitionDate" xlink:label="loc_ifrs-fullPropertyPlantAndEquipmentRecognisedAsOfAcquisitionDate_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullPropertyPlantAndEquipmentRecognisedAsOfAcquisitionDate_20" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TradeAndOtherPayablesRecognisedAsOfAcquisitionDate" xlink:label="loc_ifrs-fullTradeAndOtherPayablesRecognisedAsOfAcquisitionDate_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullTradeAndOtherPayablesRecognisedAsOfAcquisitionDate_20" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IdentifiableAssetsAcquiredLiabilitiesAssumed" xlink:label="loc_ifrs-fullIdentifiableAssetsAcquiredLiabilitiesAssumed_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullIdentifiableAssetsAcquiredLiabilitiesAssumed_20" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_LossOnAcquisition" xlink:label="loc_PNRLLossOnAcquisition_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLLossOnAcquisition_20" xlink:type="arc" order="10" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SummaryOfCostOfAcquisitionDetailsParenthetical" xlink:title="00000038 - Disclosure - SUMMARY OF COST OF ACQUISITION (Details) (Parenthetical)">
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ReserveQuantitiesLineItems" xlink:label="loc_srtReserveQuantitiesLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:label="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_LegalEntityAxis" xlink:label="loc_deiLegalEntityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:to="loc_deiLegalEntityAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_deiEntityDomain" xlink:to="loc_PNRLNorthAmericanNickelIncMember_10" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_srtProvedDevelopedAndUndevelopedOilAndGasReserveQuantitiesTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_OrdinarySharesMember" xlink:label="loc_ifrs-fullOrdinarySharesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_ifrs-fullOrdinarySharesMember_10" xlink:type="arc" order="12" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsPercent" xlink:label="loc_PNRLWarrantsPercent_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_PNRLWarrantsPercent_60" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfSharesOutstanding" xlink:label="loc_ifrs-fullNumberOfSharesOutstanding_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_ifrs-fullNumberOfSharesOutstanding_60" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_OutstandingCapitalPercent" xlink:label="loc_PNRLOutstandingCapitalPercent_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_PNRLOutstandingCapitalPercent_60" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_CapitalToBeIssued" xlink:label="loc_PNRLCapitalToBeIssued_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_PNRLCapitalToBeIssued_60" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfWarrants" xlink:label="loc_PNRLFairValueOfWarrants_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_PNRLFairValueOfWarrants_60" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfShares" xlink:label="loc_PNRLFairValueOfShares_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_PNRLFairValueOfShares_60" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExpectedLifeOfWarrants" xlink:label="loc_PNRLExpectedLifeOfWarrants_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_PNRLExpectedLifeOfWarrants_60" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ExpectedDividendAsPercentageShareOptionsGranted" xlink:label="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_60" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfRiskFreeInterestRateShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_60" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfExpectedVolatilityShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtReserveQuantitiesLineItems" xlink:to="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_60" xlink:type="arc" order="9" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfFairValueAssumptionsOfOptionsAndWarrantsDetails" xlink:title="00000039 - Disclosure - SCHEDULE OF FAIR VALUE ASSUMPTIONS OF OPTIONS AND WARRANTS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_StatementOfChangesInEquityTable" xlink:label="loc_ifrs-fullStatementOfChangesInEquityTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsMember" xlink:label="loc_PNRLWarrantsMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLWarrantsMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_OptionsMember" xlink:label="loc_PNRLOptionsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLOptionsMember_10" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_RangeAxis" xlink:label="loc_ifrs-fullRangeAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullRangeAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_RangesMember" xlink:label="loc_ifrs-fullRangesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullRangeAxis" xlink:to="loc_ifrs-fullRangesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_RangesMember" xlink:label="loc_ifrs-fullRangesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullRangeAxis" xlink:to="loc_ifrs-fullRangesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_BottomOfRangeMember" xlink:label="loc_ifrs-fullBottomOfRangeMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullRangesMember" xlink:to="loc_ifrs-fullBottomOfRangeMember_20" xlink:type="arc" order="22" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TopOfRangeMember" xlink:label="loc_ifrs-fullTopOfRangeMember_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullRangesMember" xlink:to="loc_ifrs-fullTopOfRangeMember_30" xlink:type="arc" order="32" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ExpectedDividendAsPercentageShareOptionsGranted" xlink:label="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_70" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_WeightedAverageSharePriceShareOptionsGranted2019" xlink:label="loc_ifrs-fullWeightedAverageSharePriceShareOptionsGranted2019_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullWeightedAverageSharePriceShareOptionsGranted2019_70" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfExpectedVolatilityShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_70" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfRiskFreeInterestRateShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_70" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_WeightedAverageRemainingContractualLifeOfOutstandingShareOptions2019" xlink:label="loc_ifrs-fullWeightedAverageRemainingContractualLifeOfOutstandingShareOptions2019_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullWeightedAverageRemainingContractualLifeOfOutstandingShareOptions2019_70" xlink:type="arc" order="4" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/AmalgamationDetailsNarrative" xlink:title="00000040 - Disclosure - AMALGAMATION (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:label="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLNorthAmericanNickelIncMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsAxis" xlink:label="loc_ifrs-fullTypesOfContractsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullTypesOfContractsAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsMember" xlink:label="loc_ifrs-fullTypesOfContractsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullTypesOfContractsAxis" xlink:to="loc_ifrs-fullTypesOfContractsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsMember" xlink:label="loc_ifrs-fullTypesOfContractsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullTypesOfContractsAxis" xlink:to="loc_ifrs-fullTypesOfContractsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_AmalgamationAgreementMember" xlink:label="loc_PNRLAmalgamationAgreementMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullTypesOfContractsMember" xlink:to="loc_PNRLAmalgamationAgreementMember_0" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ReverseTakeoverTransactionMember" xlink:label="loc_PNRLReverseTakeoverTransactionMember_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullTypesOfContractsMember" xlink:to="loc_PNRLReverseTakeoverTransactionMember_60" xlink:type="arc" order="61" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_LegalEntityAxis" xlink:label="loc_deiLegalEntityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_deiLegalEntityAxis" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PremiumNickelResourcesCorporationMember" xlink:label="loc_PNRLPremiumNickelResourcesCorporationMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_deiEntityDomain" xlink:to="loc_PNRLPremiumNickelResourcesCorporationMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_deiEntityDomain" xlink:to="loc_PNRLNorthAmericanNickelIncMember_40" xlink:type="arc" order="41" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PreferenceSharesMember" xlink:label="loc_ifrs-fullPreferenceSharesMember_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_ifrs-fullPreferenceSharesMember_80" xlink:type="arc" order="81" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ShareExchangeRatioForRto" xlink:label="loc_PNRLShareExchangeRatioForRto_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLShareExchangeRatioForRto_120" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfNatureAndPurposeOfReservesWithinEquity" xlink:label="loc_ifrs-fullDescriptionOfNatureAndPurposeOfReservesWithinEquity_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfNatureAndPurposeOfReservesWithinEquity_120" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfSharesIssued" xlink:label="loc_ifrs-fullNumberOfSharesIssued_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfSharesIssued_120" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_OutstandingNumberOfSharesSubscribedByRelatedParty" xlink:label="loc_PNRLOutstandingNumberOfSharesSubscribedByRelatedParty_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLOutstandingNumberOfSharesSubscribedByRelatedParty_120" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_OwnershipPercentageOfPostReverseTakeoverTransaction" xlink:label="loc_PNRLOwnershipPercentageOfPostReverseTakeoverTransaction_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLOwnershipPercentageOfPostReverseTakeoverTransaction_120" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfShareOptionsGrantedInSharebasedPaymentArrangement" xlink:label="loc_ifrs-fullNumberOfShareOptionsGrantedInSharebasedPaymentArrangement_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfShareOptionsGrantedInSharebasedPaymentArrangement_120" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfUnvestedOptionsOutstanding" xlink:label="loc_PNRLNumberOfUnvestedOptionsOutstanding_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfUnvestedOptionsOutstanding_120" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_WeightedAverageFairValueAtMeasurementDateShareOptionsGranted" xlink:label="loc_ifrs-fullWeightedAverageFairValueAtMeasurementDateShareOptionsGranted_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullWeightedAverageFairValueAtMeasurementDateShareOptionsGranted_120" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfOutstandingShareOptions" xlink:label="loc_ifrs-fullNumberOfOutstandingShareOptions_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfOutstandingShareOptions_120" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfOtherEquityInstrumentsOutstandingInSharebasedPaymentArrangement" xlink:label="loc_ifrs-fullNumberOfOtherEquityInstrumentsOutstandingInSharebasedPaymentArrangement_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfOtherEquityInstrumentsOutstandingInSharebasedPaymentArrangement_120" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ConversionOfStockSharesIssued" xlink:label="loc_PNRLConversionOfStockSharesIssued_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLConversionOfStockSharesIssued_120" xlink:type="arc" order="10" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ConversionOfStockSharesToBeIssued" xlink:label="loc_PNRLConversionOfStockSharesToBeIssued_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLConversionOfStockSharesToBeIssued_120" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfOptionsWarrantsAndPreferredShares" xlink:label="loc_PNRLFairValueOfOptionsWarrantsAndPreferredShares_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFairValueOfOptionsWarrantsAndPreferredShares_120" xlink:type="arc" order="12" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_TransactionCosts" xlink:label="loc_PNRLTransactionCosts_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLTransactionCosts_120" xlink:type="arc" order="13" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ParValuePerShare" xlink:label="loc_ifrs-fullParValuePerShare_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullParValuePerShare_120" xlink:type="arc" order="14" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ProfitLoss" xlink:label="loc_ifrs-fullProfitLoss_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullProfitLoss_120" xlink:type="arc" order="15" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfReceivablesAndOtherCurrentAssetsDetails" xlink:title="00000041 - Disclosure - SCHEDULE OF RECEIVABLES AND OTHER CURRENT ASSETS (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SummaryOfExplorationAndEvaluationAssetsDetails" xlink:title="00000042 - Disclosure - SUMMARY OF EXPLORATION AND EVALUATION ASSETS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfFairValueMeasurementOfAssetsTable" xlink:label="loc_ifrs-fullDisclosureOfFairValueMeasurementOfAssetsTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfFairValueMeasurementOfAssetsTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfAssetsAxis" xlink:label="loc_ifrs-fullClassesOfAssetsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfFairValueMeasurementOfAssetsTable" xlink:to="loc_ifrs-fullClassesOfAssetsAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfAssetsMember" xlink:label="loc_ifrs-fullClassesOfAssetsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullClassesOfAssetsAxis" xlink:to="loc_ifrs-fullClassesOfAssetsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfAssetsMember" xlink:label="loc_ifrs-fullClassesOfAssetsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullClassesOfAssetsAxis" xlink:to="loc_ifrs-fullClassesOfAssetsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExplorationAndEvaluationAssetsArisingFromExplorationMember" xlink:label="loc_PNRLExplorationAndEvaluationAssetsArisingFromExplorationMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullClassesOfAssetsMember" xlink:to="loc_PNRLExplorationAndEvaluationAssetsArisingFromExplorationMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_BusinessCombinationsAxis" xlink:label="loc_ifrs-fullBusinessCombinationsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfFairValueMeasurementOfAssetsTable" xlink:to="loc_ifrs-fullBusinessCombinationsAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForBusinessCombinationsMember" xlink:label="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullBusinessCombinationsAxis" xlink:to="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForBusinessCombinationsMember" xlink:label="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullBusinessCombinationsAxis" xlink:to="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SelebiMember" xlink:label="loc_PNRLSelebiMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" xlink:to="loc_PNRLSelebiMember_0" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SelkirkMember" xlink:label="loc_PNRLSelkirkMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" xlink:to="loc_PNRLSelkirkMember_10" xlink:type="arc" order="12" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GeographicalAreasAxis" xlink:label="loc_ifrs-fullGeographicalAreasAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfFairValueMeasurementOfAssetsTable" xlink:to="loc_ifrs-fullGeographicalAreasAxis" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GeographicalAreasMember" xlink:label="loc_ifrs-fullGeographicalAreasMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullGeographicalAreasAxis" xlink:to="loc_ifrs-fullGeographicalAreasMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GeographicalAreasMember" xlink:label="loc_ifrs-fullGeographicalAreasMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullGeographicalAreasAxis" xlink:to="loc_ifrs-fullGeographicalAreasMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BWMember" xlink:label="loc_PNRLBWMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullGeographicalAreasMember" xlink:to="loc_PNRLBWMember_0" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IntangibleExplorationAndEvaluationAssets" xlink:label="loc_ifrs-fullIntangibleExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullIntangibleExplorationAndEvaluationAssets_100" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughSiteAdministrationExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughSiteAdministrationExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughSiteAdministrationExplorationAndEvaluationAssets_100" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughCareAndMaintenanceExpensesExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughCareAndMaintenanceExpensesExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughCareAndMaintenanceExpensesExplorationAndEvaluationAssets_100" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughGeologyExpensesExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughGeologyExpensesExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughGeologyExpensesExplorationAndEvaluationAssets_100" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughDrillingExpensesExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughDrillingExpensesExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughDrillingExpensesExplorationAndEvaluationAssets_100" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughGeophysicsExpensesExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughGeophysicsExpensesExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughGeophysicsExpensesExplorationAndEvaluationAssets_100" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughEngineeringExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughEngineeringExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughEngineeringExplorationAndEvaluationAssets_100" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughESGExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughESGExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughESGExplorationAndEvaluationAssets_100" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughMetallurgyAndMPExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughMetallurgyAndMPExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughMetallurgyAndMPExplorationAndEvaluationAssets_100" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughTechnicalStudiesExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughTechnicalStudiesExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughTechnicalStudiesExplorationAndEvaluationAssets_100" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughHealthAndSafetyExplorationAndEvaluationAssets" xlink:label="loc_PNRLIncreaseThroughHealthAndSafetyExplorationAndEvaluationAssets_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughHealthAndSafetyExplorationAndEvaluationAssets_100" xlink:type="arc" order="10" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IncreaseThroughImpactOfForeignCurrencyTranslation" xlink:label="loc_PNRLIncreaseThroughImpactOfForeignCurrencyTranslation_100" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIncreaseThroughImpactOfForeignCurrencyTranslation_100" xlink:type="arc" order="11" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ExplorationAndEvaluationAssetsDetailsNarrative" xlink:title="00000043 - Disclosure - EXPLORATION AND EVALUATION ASSETS (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfBusinessCombinationsTable" xlink:label="loc_ifrs-fullDisclosureOfBusinessCombinationsTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfBusinessCombinationsTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_BusinessCombinationsAxis" xlink:label="loc_ifrs-fullBusinessCombinationsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfBusinessCombinationsTable" xlink:to="loc_ifrs-fullBusinessCombinationsAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForBusinessCombinationsMember" xlink:label="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullBusinessCombinationsAxis" xlink:to="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForBusinessCombinationsMember" xlink:label="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullBusinessCombinationsAxis" xlink:to="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SelebiMember" xlink:label="loc_PNRLSelebiMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" xlink:to="loc_PNRLSelebiMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SelkirkMember" xlink:label="loc_PNRLSelkirkMember_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForBusinessCombinationsMember" xlink:to="loc_PNRLSelkirkMember_30" xlink:type="arc" order="31" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IdentifiableAssetsAcquiredLiabilitiesAssumed" xlink:label="loc_ifrs-fullIdentifiableAssetsAcquiredLiabilitiesAssumed_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullIdentifiableAssetsAcquiredLiabilitiesAssumed_80" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ClosingPayable" xlink:label="loc_PNRLClosingPayable_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLClosingPayable_80" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SecondInstallmentOfAssetPurchasePrice" xlink:label="loc_PNRLSecondInstallmentOfAssetPurchasePrice_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLSecondInstallmentOfAssetPurchasePrice_80" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ThirdInstallmentOfAssetPurchasePrice" xlink:label="loc_PNRLThirdInstallmentOfAssetPurchasePrice_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLThirdInstallmentOfAssetPurchasePrice_80" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PaymentOfCareAndMaintenanceExpense" xlink:label="loc_PNRLPaymentOfCareAndMaintenanceExpense_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLPaymentOfCareAndMaintenanceExpense_80" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_FinancialAssetsRecognisedAsOfAcquisitionDate" xlink:label="loc_ifrs-fullFinancialAssetsRecognisedAsOfAcquisitionDate_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullFinancialAssetsRecognisedAsOfAcquisitionDate_80" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PaymentOfCareAndMaintenanceFundings" xlink:label="loc_PNRLPaymentOfCareAndMaintenanceFundings_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLPaymentOfCareAndMaintenanceFundings_80" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PaymentOfSecondInstalment" xlink:label="loc_PNRLPaymentOfSecondInstalment_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLPaymentOfSecondInstalment_80" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PaymentOfThirdInstalment" xlink:label="loc_PNRLPaymentOfThirdInstalment_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLPaymentOfThirdInstalment_80" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PaymentsForExplorationAndEvaluationExpenses" xlink:label="loc_ifrs-fullPaymentsForExplorationAndEvaluationExpenses_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullPaymentsForExplorationAndEvaluationExpenses_80" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExplorationAndLicenseRelatedExpenditure" xlink:label="loc_PNRLExplorationAndLicenseRelatedExpenditure_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLExplorationAndLicenseRelatedExpenditure_80" xlink:type="arc" order="10" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SummaryOfPropertyPlantAndEquipmentDetails" xlink:title="00000044 - Disclosure - SUMMARY OF PROPERTY, PLANT AND EQUIPMENT (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfReconciliationOfChangesInGoodwillTable" xlink:label="loc_ifrs-fullDisclosureOfReconciliationOfChangesInGoodwillTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfReconciliationOfChangesInGoodwillTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CarryingAmountAccumulatedDepreciationAmortisationAndImpairmentAndGrossCarryingAmountAxis" xlink:label="loc_ifrs-fullCarryingAmountAccumulatedDepreciationAmortisationAndImpairmentAndGrossCarryingAmountAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfReconciliationOfChangesInGoodwillTable" xlink:to="loc_ifrs-fullCarryingAmountAccumulatedDepreciationAmortisationAndImpairmentAndGrossCarryingAmountAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CarryingAmountMember" xlink:label="loc_ifrs-fullCarryingAmountMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCarryingAmountAccumulatedDepreciationAmortisationAndImpairmentAndGrossCarryingAmountAxis" xlink:to="loc_ifrs-fullCarryingAmountMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CarryingAmountMember" xlink:label="loc_ifrs-fullCarryingAmountMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCarryingAmountAccumulatedDepreciationAmortisationAndImpairmentAndGrossCarryingAmountAxis" xlink:to="loc_ifrs-fullCarryingAmountMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GrossCarryingAmountMember" xlink:label="loc_ifrs-fullGrossCarryingAmountMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullCarryingAmountMember" xlink:to="loc_ifrs-fullGrossCarryingAmountMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_AccumulatedDepreciationMember" xlink:label="loc_PNRLAccumulatedDepreciationMember_160" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullCarryingAmountMember" xlink:to="loc_PNRLAccumulatedDepreciationMember_160" xlink:type="arc" order="161" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfPropertyPlantAndEquipmentAxis" xlink:label="loc_ifrs-fullClassesOfPropertyPlantAndEquipmentAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfReconciliationOfChangesInGoodwillTable" xlink:to="loc_ifrs-fullClassesOfPropertyPlantAndEquipmentAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PropertyPlantAndEquipmentMember" xlink:label="loc_ifrs-fullPropertyPlantAndEquipmentMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullClassesOfPropertyPlantAndEquipmentAxis" xlink:to="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PropertyPlantAndEquipmentMember" xlink:label="loc_ifrs-fullPropertyPlantAndEquipmentMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullClassesOfPropertyPlantAndEquipmentAxis" xlink:to="loc_ifrs-fullPropertyPlantAndEquipmentMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LandMember" xlink:label="loc_ifrs-fullLandMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_ifrs-fullLandMember_0" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_BuildingsMember" xlink:label="loc_ifrs-fullBuildingsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_ifrs-fullBuildingsMember_10" xlink:type="arc" order="12" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_FixturesAndFittingsMember" xlink:label="loc_ifrs-fullFixturesAndFittingsMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_ifrs-fullFixturesAndFittingsMember_20" xlink:type="arc" order="22" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExplorationEquipmentMember" xlink:label="loc_PNRLExplorationEquipmentMember_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_PNRLExplorationEquipmentMember_30" xlink:type="arc" order="32" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_GeneratorMember" xlink:label="loc_PNRLGeneratorMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_PNRLGeneratorMember_40" xlink:type="arc" order="42" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_VehiclesMember" xlink:label="loc_ifrs-fullVehiclesMember_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_ifrs-fullVehiclesMember_50" xlink:type="arc" order="52" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ComputerEquipmentsAndSoftwareMember" xlink:label="loc_PNRLComputerEquipmentsAndSoftwareMember_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullPropertyPlantAndEquipmentMember" xlink:to="loc_PNRLComputerEquipmentsAndSoftwareMember_60" xlink:type="arc" order="62" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PropertyPlantAndEquipment" xlink:label="loc_ifrs-fullPropertyPlantAndEquipment_650" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullPropertyPlantAndEquipment_650" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ImpactOfFXTranslationBusinessCombinationsPropertyPlantAndEquipment" xlink:label="loc_PNRLImpactOfFXTranslationBusinessCombinationsPropertyPlantAndEquipment_650" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLImpactOfFXTranslationBusinessCombinationsPropertyPlantAndEquipment_650" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DepreciationPropertyPlantAndEquipment" xlink:label="loc_ifrs-fullDepreciationPropertyPlantAndEquipment_650" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDepreciationPropertyPlantAndEquipment_650" xlink:type="arc" order="2" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SummaryOfTradePayablesAndAccruedLiabilitiesDetails" xlink:title="00000045 - Disclosure - SUMMARY OF TRADE PAYABLES AND ACCRUED LIABILITIES (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfFairValueOfLenderWarrantsAssumptionsDetails" xlink:title="00000046 - Disclosure - SCHEDULE OF FAIR VALUE OF LENDER WARRANTS ASSUMPTIONS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_StatementOfChangesInEquityTable" xlink:label="loc_ifrs-fullStatementOfChangesInEquityTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_LenderWarrantsMember" xlink:label="loc_PNRLLenderWarrantsMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLLenderWarrantsMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ExpectedDividendAsPercentageShareOptionsGranted" xlink:label="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_20" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_StockPrice" xlink:label="loc_PNRLStockPrice_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLStockPrice_20" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfExpectedVolatilityShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_20" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfRiskFreeInterestRateShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_20" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExpectedLifeOfOptionsGranted" xlink:label="loc_PNRLExpectedLifeOfOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLExpectedLifeOfOptionsGranted_20" xlink:type="arc" order="4" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/PromissoryNoteDetailsNarrative" xlink:title="00000047 - Disclosure - PROMISSORY NOTE (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:label="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PinnacleIslandLPMember" xlink:label="loc_PNRLPinnacleIslandLPMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLPinnacleIslandLPMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsAxis" xlink:label="loc_ifrs-fullTypesOfContractsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullTypesOfContractsAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsMember" xlink:label="loc_ifrs-fullTypesOfContractsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullTypesOfContractsAxis" xlink:to="loc_ifrs-fullTypesOfContractsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsMember" xlink:label="loc_ifrs-fullTypesOfContractsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullTypesOfContractsAxis" xlink:to="loc_ifrs-fullTypesOfContractsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_AmendedAndRestatedPromissoryNoteMember" xlink:label="loc_PNRLAmendedAndRestatedPromissoryNoteMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullTypesOfContractsMember" xlink:to="loc_PNRLAmendedAndRestatedPromissoryNoteMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_TitleOfIndividualAxis" xlink:label="loc_srtTitleOfIndividualAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_srtTitleOfIndividualAxis" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_TitleOfIndividualWithRelationshipToEntityDomain" xlink:label="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_srtTitleOfIndividualAxis" xlink:to="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_TitleOfIndividualWithRelationshipToEntityDomain" xlink:label="loc_srtTitleOfIndividualWithRelationshipToEntityDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_srtTitleOfIndividualAxis" xlink:to="loc_srtTitleOfIndividualWithRelationshipToEntityDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_LenderMember" xlink:label="loc_PNRLLenderMember_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" xlink:to="loc_PNRLLenderMember_30" xlink:type="arc" order="31" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_LenderWarrantsMember" xlink:label="loc_PNRLLenderWarrantsMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLLenderWarrantsMember_40" xlink:type="arc" order="41" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsMember" xlink:label="loc_PNRLWarrantsMember_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLWarrantsMember_50" xlink:type="arc" order="51" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CorporateLoans" xlink:label="loc_ifrs-fullCorporateLoans_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullCorporateLoans_120" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LoansReceived" xlink:label="loc_ifrs-fullLoansReceived_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullLoansReceived_120" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_FeeAndCommissionExpense" xlink:label="loc_ifrs-fullFeeAndCommissionExpense_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullFeeAndCommissionExpense_120" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_Borrowings" xlink:label="loc_ifrs-fullBorrowings_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullBorrowings_120" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_BorrowingsInterestRate" xlink:label="loc_ifrs-fullBorrowingsInterestRate_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullBorrowingsInterestRate_120" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_BorrowingsMaturity" xlink:label="loc_ifrs-fullBorrowingsMaturity_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullBorrowingsMaturity_120" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BorrowingsExtendedMaturity" xlink:label="loc_PNRLBorrowingsExtendedMaturity_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLBorrowingsExtendedMaturity_120" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_RestatementFees" xlink:label="loc_PNRLRestatementFees_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLRestatementFees_120" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NontransferrableCommonSharePurchaseWarrants" xlink:label="loc_PNRLNontransferrableCommonSharePurchaseWarrants_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNontransferrableCommonSharePurchaseWarrants_120" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantExercisePrice" xlink:label="loc_PNRLWarrantExercisePrice_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLWarrantExercisePrice_120" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfWarrantsIssued" xlink:label="loc_PNRLNumberOfWarrantsIssued_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfWarrantsIssued_120" xlink:type="arc" order="10" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_InterestPayable" xlink:label="loc_ifrs-fullInterestPayable_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullInterestPayable_120" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfWarrantsLiability" xlink:label="loc_PNRLFairValueOfWarrantsLiability_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFairValueOfWarrantsLiability_120" xlink:type="arc" order="12" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FeesAndFairValueOfWarrants" xlink:label="loc_PNRLFeesAndFairValueOfWarrants_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFeesAndFairValueOfWarrants_120" xlink:type="arc" order="13" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfDetailsOfLeaseLiabilitiesDetails" xlink:title="00000048 - Disclosure - SCHEDULE OF DETAILS OF LEASE LIABILITIES (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/LeaseLiabilityDetailsNarrative" xlink:title="00000049 - Disclosure - LEASE LIABILITY (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:label="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_TuliTourismPtyLtdMember" xlink:label="loc_PNRLTuliTourismPtyLtdMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLTuliTourismPtyLtdMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NonadjustingEventsAfterReportingPeriodAxis" xlink:label="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NonadjustingEventsMember" xlink:label="loc_ifrs-fullNonadjustingEventsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" xlink:to="loc_ifrs-fullNonadjustingEventsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NonadjustingEventsMember" xlink:label="loc_ifrs-fullNonadjustingEventsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" xlink:to="loc_ifrs-fullNonadjustingEventsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NonadjustingEventMember" xlink:label="loc_PNRLNonadjustingEventMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullNonadjustingEventsMember" xlink:to="loc_PNRLNonadjustingEventMember_20" xlink:type="arc" order="22" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_AssetPurchasePricePayableToSeller" xlink:label="loc_PNRLAssetPurchasePricePayableToSeller_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLAssetPurchasePricePayableToSeller_60" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LongtermDeposits" xlink:label="loc_ifrs-fullLongtermDeposits_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullLongtermDeposits_60" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_InstallmentOfAssetPurchasePricePayable" xlink:label="loc_PNRLInstallmentOfAssetPurchasePricePayable_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLInstallmentOfAssetPurchasePricePayable_60" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CurrentInterestPayable" xlink:label="loc_ifrs-fullCurrentInterestPayable_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullCurrentInterestPayable_60" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NoncurrentInterestPayable" xlink:label="loc_ifrs-fullNoncurrentInterestPayable_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNoncurrentInterestPayable_60" xlink:type="arc" order="4" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfOfFairValueOfBrokerWarrantsAssumptionsDetails" xlink:title="00000050 - Disclosure - SCHEDULE OF OF FAIR VALUE OF BROKER WARRANTS ASSUMPTIONS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_StatementOfChangesInEquityTable" xlink:label="loc_ifrs-fullStatementOfChangesInEquityTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BrokerWarrantsMember" xlink:label="loc_PNRLBrokerWarrantsMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLBrokerWarrantsMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ExpectedDividendAsPercentageShareOptionsGranted" xlink:label="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullExpectedDividendAsPercentageShareOptionsGranted_20" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_StockPrice" xlink:label="loc_PNRLStockPrice_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLStockPrice_20" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfExpectedVolatilityShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfExpectedVolatilityShareOptionsGranted_20" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfRiskFreeInterestRateShareOptionsGranted" xlink:label="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfRiskFreeInterestRateShareOptionsGranted_20" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExpectedLifeOfOptionsGranted" xlink:label="loc_PNRLExpectedLifeOfOptionsGranted_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLExpectedLifeOfOptionsGranted_20" xlink:type="arc" order="4" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfWarrantActivityDetails" xlink:title="00000051 - Disclosure - SCHEDULE OF WARRANT ACTIVITY (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfNumberAndWeightedAverageRemainingContractualLifeOfOutstandingWarrantsDetails" xlink:title="00000052 - Disclosure - SCHEDULE OF NUMBER AND WEIGHTED AVERAGE REMAINING CONTRACTUAL LIFE OF OUTSTANDING WARRANTS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementTable" xlink:label="loc_PNRLIfrsStatementTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIfrsStatementTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_TypesOfWarrantsAxis" xlink:label="loc_PNRLTypesOfWarrantsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_PNRLIfrsStatementTable" xlink:to="loc_PNRLTypesOfWarrantsAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_TypesOfWarrantsDomain" xlink:label="loc_PNRLTypesOfWarrantsDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_PNRLTypesOfWarrantsAxis" xlink:to="loc_PNRLTypesOfWarrantsDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_TypesOfWarrantsDomain" xlink:label="loc_PNRLTypesOfWarrantsDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_PNRLTypesOfWarrantsAxis" xlink:to="loc_PNRLTypesOfWarrantsDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsExpiringAprilSixteenTwoThousandTwentyThreeMember" xlink:label="loc_PNRLWarrantsExpiringAprilSixteenTwoThousandTwentyThreeMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLTypesOfWarrantsDomain" xlink:to="loc_PNRLWarrantsExpiringAprilSixteenTwoThousandTwentyThreeMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsExpiringAugustThreeTwoThousandTwentyFourMember" xlink:label="loc_PNRLWarrantsExpiringAugustThreeTwoThousandTwentyFourMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLTypesOfWarrantsDomain" xlink:to="loc_PNRLWarrantsExpiringAugustThreeTwoThousandTwentyFourMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsExpiringNovemberTwentyFourTwoThousandTwentyFiveMember" xlink:label="loc_PNRLWarrantsExpiringNovemberTwentyFourTwoThousandTwentyFiveMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLTypesOfWarrantsDomain" xlink:to="loc_PNRLWarrantsExpiringNovemberTwentyFourTwoThousandTwentyFiveMember_40" xlink:type="arc" order="41" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsExpiringFebruaryTwentyFourTwoThousandTwentyFiveMember" xlink:label="loc_PNRLWarrantsExpiringFebruaryTwentyFourTwoThousandTwentyFiveMember_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLTypesOfWarrantsDomain" xlink:to="loc_PNRLWarrantsExpiringFebruaryTwentyFourTwoThousandTwentyFiveMember_50" xlink:type="arc" order="51" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantsExpiringMarchTwentyTwoTwoThousandTwentyFourMember" xlink:label="loc_PNRLWarrantsExpiringMarchTwentyTwoTwoThousandTwentyFourMember_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLTypesOfWarrantsDomain" xlink:to="loc_PNRLWarrantsExpiringMarchTwentyTwoTwoThousandTwentyFourMember_70" xlink:type="arc" order="71" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfWarrantsOutstanding" xlink:label="loc_PNRLNumberOfWarrantsOutstanding_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfWarrantsOutstanding_120" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExercisePriceOfWarrant" xlink:label="loc_PNRLExercisePriceOfWarrant_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLExercisePriceOfWarrant_120" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WeightedAverageRemainingContractualLifeOfOutstandingWarrant" xlink:label="loc_PNRLWeightedAverageRemainingContractualLifeOfOutstandingWarrant_120" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLWeightedAverageRemainingContractualLifeOfOutstandingWarrant_120" xlink:type="arc" order="2" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfNumberAndWeightedAverageRemainingContractualLifeOfOutstandingWarrantsDetailsParenthetical" xlink:title="00000053 - Disclosure - SCHEDULE OF NUMBER AND WEIGHTED AVERAGE REMAINING CONTRACTUAL LIFE OF OUTSTANDING WARRANTS (Details) (Parenthetical)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementTable" xlink:label="loc_PNRLIfrsStatementTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIfrsStatementTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_StatementScenarioAxis" xlink:label="loc_srtStatementScenarioAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_PNRLIfrsStatementTable" xlink:to="loc_srtStatementScenarioAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ScenarioUnspecifiedDomain" xlink:label="loc_srtScenarioUnspecifiedDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_srtStatementScenarioAxis" xlink:to="loc_srtScenarioUnspecifiedDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ScenarioUnspecifiedDomain" xlink:label="loc_srtScenarioUnspecifiedDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_srtStatementScenarioAxis" xlink:to="loc_srtScenarioUnspecifiedDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ScenarioForecastMember" xlink:label="loc_srtScenarioForecastMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtScenarioUnspecifiedDomain" xlink:to="loc_srtScenarioForecastMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfWarrantsOutstanding" xlink:label="loc_PNRLNumberOfWarrantsOutstanding_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfWarrantsOutstanding_30" xlink:type="arc" order="0" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfDeferredShareUnitPlanHaveBeenGrantedDetails" xlink:title="00000054 - Disclosure - SCHEDULE OF DEFERRED SHARE UNIT PLAN HAVE BEEN GRANTED (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTermsAndConditionsOfSharebasedPaymentArrangementTable" xlink:label="loc_ifrs-fullDisclosureOfTermsAndConditionsOfSharebasedPaymentArrangementTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTermsAndConditionsOfSharebasedPaymentArrangementTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfSharebasedPaymentArrangementsAxis" xlink:label="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTermsAndConditionsOfSharebasedPaymentArrangementTable" xlink:to="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_SharebasedPaymentArrangementsMember" xlink:label="loc_ifrs-fullSharebasedPaymentArrangementsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" xlink:to="loc_ifrs-fullSharebasedPaymentArrangementsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_SharebasedPaymentArrangementsMember" xlink:label="loc_ifrs-fullSharebasedPaymentArrangementsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" xlink:to="loc_ifrs-fullSharebasedPaymentArrangementsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_DeferredShareUnitPlanMember" xlink:label="loc_PNRLDeferredShareUnitPlanMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullSharebasedPaymentArrangementsMember" xlink:to="loc_PNRLDeferredShareUnitPlanMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfSharesOutstanding" xlink:label="loc_ifrs-fullNumberOfSharesOutstanding_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfSharesOutstanding_40" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IncreaseDecreaseInNumberOfSharesOutstanding" xlink:label="loc_ifrs-fullIncreaseDecreaseInNumberOfSharesOutstanding_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullIncreaseDecreaseInNumberOfSharesOutstanding_40" xlink:type="arc" order="1" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ShareCapitalWarrantsAndOptionsDetailsNarrative" xlink:title="00000055 - Disclosure - SHARE CAPITAL, WARRANTS AND OPTIONS (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_StatementOfChangesInEquityTable" xlink:label="loc_ifrs-fullStatementOfChangesInEquityTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfShareCapitalAxis" xlink:label="loc_ifrs-fullClassesOfShareCapitalAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullClassesOfShareCapitalAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfShareCapitalMember" xlink:label="loc_ifrs-fullClassesOfShareCapitalMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullClassesOfShareCapitalAxis" xlink:to="loc_ifrs-fullClassesOfShareCapitalMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfShareCapitalMember" xlink:label="loc_ifrs-fullClassesOfShareCapitalMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullClassesOfShareCapitalAxis" xlink:to="loc_ifrs-fullClassesOfShareCapitalMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SeriesOneConvertiblePreferredSharesMember" xlink:label="loc_PNRLSeriesOneConvertiblePreferredSharesMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullClassesOfShareCapitalMember" xlink:to="loc_PNRLSeriesOneConvertiblePreferredSharesMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_OrdinarySharesMember" xlink:label="loc_ifrs-fullOrdinarySharesMember_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullClassesOfShareCapitalMember" xlink:to="loc_ifrs-fullOrdinarySharesMember_80" xlink:type="arc" order="82" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ComponentsOfEquityAxis" xlink:label="loc_ifrs-fullComponentsOfEquityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullComponentsOfEquityAxis" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EquityMember" xlink:label="loc_ifrs-fullEquityMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullComponentsOfEquityAxis" xlink:to="loc_ifrs-fullEquityMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BrokeredPrivatePlacementMember" xlink:label="loc_PNRLBrokeredPrivatePlacementMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLBrokeredPrivatePlacementMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BrokerWarrantsMember" xlink:label="loc_PNRLBrokerWarrantsMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLBrokerWarrantsMember_40" xlink:type="arc" order="41" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_OrdinarySharesMember" xlink:label="loc_ifrs-fullOrdinarySharesMember_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_ifrs-fullOrdinarySharesMember_60" xlink:type="arc" order="61" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NonBrokeredPrivatePlacementMember" xlink:label="loc_PNRLNonBrokeredPrivatePlacementMember_80" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEquityMember" xlink:to="loc_PNRLNonBrokeredPrivatePlacementMember_80" xlink:type="arc" order="81" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_TitleOfIndividualAxis" xlink:label="loc_srtTitleOfIndividualAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_srtTitleOfIndividualAxis" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_TitleOfIndividualWithRelationshipToEntityDomain" xlink:label="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_srtTitleOfIndividualAxis" xlink:to="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_TitleOfIndividualWithRelationshipToEntityDomain" xlink:label="loc_srtTitleOfIndividualWithRelationshipToEntityDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_srtTitleOfIndividualAxis" xlink:to="loc_srtTitleOfIndividualWithRelationshipToEntityDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FinderOneMember" xlink:label="loc_PNRLFinderOneMember_110" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" xlink:to="loc_PNRLFinderOneMember_110" xlink:type="arc" order="112" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FinderTwoMember" xlink:label="loc_PNRLFinderTwoMember_130" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtTitleOfIndividualWithRelationshipToEntityDomain" xlink:to="loc_PNRLFinderTwoMember_130" xlink:type="arc" order="132" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_160" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLNorthAmericanNickelIncMember_160" xlink:type="arc" order="161" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsAxis" xlink:label="loc_ifrs-fullTypesOfContractsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullTypesOfContractsAxis" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsMember" xlink:label="loc_ifrs-fullTypesOfContractsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullTypesOfContractsAxis" xlink:to="loc_ifrs-fullTypesOfContractsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfContractsMember" xlink:label="loc_ifrs-fullTypesOfContractsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullTypesOfContractsAxis" xlink:to="loc_ifrs-fullTypesOfContractsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_AmalgamationAgreementMember" xlink:label="loc_PNRLAmalgamationAgreementMember_160" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullTypesOfContractsMember" xlink:to="loc_PNRLAmalgamationAgreementMember_160" xlink:type="arc" order="162" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_LegalEntityAxis" xlink:label="loc_deiLegalEntityAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_deiLegalEntityAxis" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.sec.gov/dei/2022/dei-2022.xsd#dei_EntityDomain" xlink:label="loc_deiEntityDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_deiLegalEntityAxis" xlink:to="loc_deiEntityDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PremiumNickelResourcesCorporationMember" xlink:label="loc_PNRLPremiumNickelResourcesCorporationMember_180" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_deiEntityDomain" xlink:to="loc_PNRLPremiumNickelResourcesCorporationMember_180" xlink:type="arc" order="181" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TypesOfSharebasedPaymentArrangementsAxis" xlink:label="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullStatementOfChangesInEquityTable" xlink:to="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_SharebasedPaymentArrangementsMember" xlink:label="loc_ifrs-fullSharebasedPaymentArrangementsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" xlink:to="loc_ifrs-fullSharebasedPaymentArrangementsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_SharebasedPaymentArrangementsMember" xlink:label="loc_ifrs-fullSharebasedPaymentArrangementsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullTypesOfSharebasedPaymentArrangementsAxis" xlink:to="loc_ifrs-fullSharebasedPaymentArrangementsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_DeferredShareUnitPlanMember" xlink:label="loc_PNRLDeferredShareUnitPlanMember_220" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullSharebasedPaymentArrangementsMember" xlink:to="loc_PNRLDeferredShareUnitPlanMember_220" xlink:type="arc" order="221" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_PreferredShareConvertedToCommonShares" xlink:label="loc_PNRLPreferredShareConvertedToCommonShares_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLPreferredShareConvertedToCommonShares_270" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DescriptionOfNatureAndPurposeOfReservesWithinEquity" xlink:label="loc_ifrs-fullDescriptionOfNatureAndPurposeOfReservesWithinEquity_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDescriptionOfNatureAndPurposeOfReservesWithinEquity_270" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfSharesIssued" xlink:label="loc_ifrs-fullNumberOfSharesIssued_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfSharesIssued_270" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ParValuePerShare" xlink:label="loc_ifrs-fullParValuePerShare_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullParValuePerShare_270" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ProceedsFromIssuingShares" xlink:label="loc_ifrs-fullProceedsFromIssuingShares_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullProceedsFromIssuingShares_270" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_DescriptionForOfferingShares" xlink:label="loc_PNRLDescriptionForOfferingShares_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLDescriptionForOfferingShares_270" xlink:type="arc" order="5" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantExercisePrice" xlink:label="loc_PNRLWarrantExercisePrice_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLWarrantExercisePrice_270" xlink:type="arc" order="6" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfWarrantsOutstanding" xlink:label="loc_PNRLNumberOfWarrantsOutstanding_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfWarrantsOutstanding_270" xlink:type="arc" order="7" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_FairValueOfWarrantsLiability" xlink:label="loc_PNRLFairValueOfWarrantsLiability_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLFairValueOfWarrantsLiability_270" xlink:type="arc" order="8" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ShareIssuanceCost" xlink:label="loc_PNRLShareIssuanceCost_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLShareIssuanceCost_270" xlink:type="arc" order="9" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NumberOfSharesOutstanding" xlink:label="loc_ifrs-fullNumberOfSharesOutstanding_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullNumberOfSharesOutstanding_270" xlink:type="arc" order="10" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_CommonSharePricePerShare" xlink:label="loc_PNRLCommonSharePricePerShare_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLCommonSharePricePerShare_270" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_CashCommissionPercentage" xlink:label="loc_PNRLCashCommissionPercentage_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLCashCommissionPercentage_270" xlink:type="arc" order="12" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_OtherFeeAndCommissionIncome" xlink:label="loc_ifrs-fullOtherFeeAndCommissionIncome_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullOtherFeeAndCommissionIncome_270" xlink:type="arc" order="13" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IssueOfEquity" xlink:label="loc_ifrs-fullIssueOfEquity_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullIssueOfEquity_270" xlink:type="arc" order="14" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ShareExchangeRatioForRto" xlink:label="loc_PNRLShareExchangeRatioForRto_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLShareExchangeRatioForRto_270" xlink:type="arc" order="15" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_OutstandingNumberOfSharesSubscribedByRelatedParty" xlink:label="loc_PNRLOutstandingNumberOfSharesSubscribedByRelatedParty_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLOutstandingNumberOfSharesSubscribedByRelatedParty_270" xlink:type="arc" order="16" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SharesOfTheCompanyImmediatelyPostReverseTakeoverTransaction" xlink:label="loc_PNRLSharesOfTheCompanyImmediatelyPostReverseTakeoverTransaction_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLSharesOfTheCompanyImmediatelyPostReverseTakeoverTransaction_270" xlink:type="arc" order="17" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_AdjustmentsForSharebasedPayments" xlink:label="loc_ifrs-fullAdjustmentsForSharebasedPayments_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullAdjustmentsForSharebasedPayments_270" xlink:type="arc" order="18" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ReserveOfSharebasedPayments" xlink:label="loc_ifrs-fullReserveOfSharebasedPayments_270" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullReserveOfSharebasedPayments_270" xlink:type="arc" order="19" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfAmountsDueToRelatedPartiesIncludedInTradePayablesAndAccruedLiabilitiesDetails" xlink:title="00000056 - Disclosure - SCHEDULE OF AMOUNTS DUE TO RELATED PARTIES, INCLUDED IN TRADE PAYABLES AND ACCRUED LIABILITIES (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:label="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_DirectorsAndOfficersCompanyMember" xlink:label="loc_PNRLDirectorsAndOfficersCompanyMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLDirectorsAndOfficersCompanyMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ThreeDCapitalMember" xlink:label="loc_PNRLThreeDCapitalMember_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLThreeDCapitalMember_50" xlink:type="arc" order="51" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NorthAmericanNickelIncMember" xlink:label="loc_PNRLNorthAmericanNickelIncMember_60" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLNorthAmericanNickelIncMember_60" xlink:type="arc" order="61" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TradeAndOtherCurrentPayablesToRelatedParties" xlink:label="loc_ifrs-fullTradeAndOtherCurrentPayablesToRelatedParties_90" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullTradeAndOtherCurrentPayablesToRelatedParties_90" xlink:type="arc" order="0" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfKeyManagementCompensationDetails" xlink:title="00000057 - Disclosure - SCHEDULE OF KEY MANAGEMENT COMPENSATION (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/RelatedPartyTransactionsDetailsNarrative" xlink:title="00000058 - Disclosure - RELATED PARTY TRANSACTIONS (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:label="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CategoriesOfRelatedPartiesAxis" xlink:label="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfTransactionsBetweenRelatedPartiesTable" xlink:to="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_EntitysTotalForRelatedPartiesMember" xlink:label="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullCategoriesOfRelatedPartiesAxis" xlink:to="loc_ifrs-fullEntitysTotalForRelatedPartiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ThreeDCapitalMember" xlink:label="loc_PNRLThreeDCapitalMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullEntitysTotalForRelatedPartiesMember" xlink:to="loc_PNRLThreeDCapitalMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SaleOfStockSharesSubscribedAfterTransaction" xlink:label="loc_PNRLSaleOfStockSharesSubscribedAfterTransaction_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLSaleOfStockSharesSubscribedAfterTransaction_70" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_InvestmentsInSubsidiariesJointVenturesAndAssociates" xlink:label="loc_ifrs-fullInvestmentsInSubsidiariesJointVenturesAndAssociates_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullInvestmentsInSubsidiariesJointVenturesAndAssociates_70" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_SaleOfStockSharesOwnedAfterTransaction" xlink:label="loc_PNRLSaleOfStockSharesOwnedAfterTransaction_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLSaleOfStockSharesOwnedAfterTransaction_70" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsSaleOfStockPercentageOfOwnershipAfterTransaction" xlink:label="loc_PNRLIfrsSaleOfStockPercentageOfOwnershipAfterTransaction_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIfrsSaleOfStockPercentageOfOwnershipAfterTransaction_70" xlink:type="arc" order="3" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_RepaymentsOfBondsNotesAndDebentures" xlink:label="loc_ifrs-fullRepaymentsOfBondsNotesAndDebentures_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullRepaymentsOfBondsNotesAndDebentures_70" xlink:type="arc" order="4" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ShareIssuedPriorToRtoInConnectionWithPromissoryNotes" xlink:label="loc_PNRLShareIssuedPriorToRtoInConnectionWithPromissoryNotes_70" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLShareIssuedPriorToRtoInConnectionWithPromissoryNotes_70" xlink:type="arc" order="5" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfForeignCurrencyFinancialAssetsAndLiabilitiesDetails" xlink:title="00000059 - Disclosure - SCHEDULE OF FOREIGN CURRENCY FINANCIAL ASSETS AND LIABILITIES (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfChangesInExchangeRatesDetails" xlink:title="00000060 - Disclosure - SCHEDULE OF CHANGES IN EXCHANGE RATES (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementTable" xlink:label="loc_PNRLIfrsStatementTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLIfrsStatementTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_StatementScenarioAxis" xlink:label="loc_srtStatementScenarioAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_PNRLIfrsStatementTable" xlink:to="loc_srtStatementScenarioAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ScenarioUnspecifiedDomain" xlink:label="loc_srtScenarioUnspecifiedDomain" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_srtStatementScenarioAxis" xlink:to="loc_srtScenarioUnspecifiedDomain" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.fasb.org/srt/2022/elts/srt-2022.xsd#srt_ScenarioUnspecifiedDomain" xlink:label="loc_srtScenarioUnspecifiedDomain_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_srtStatementScenarioAxis" xlink:to="loc_srtScenarioUnspecifiedDomain_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExchangeRateStrengthenedMember" xlink:label="loc_PNRLExchangeRateStrengthenedMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtScenarioUnspecifiedDomain" xlink:to="loc_PNRLExchangeRateStrengthenedMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_ExchangeRateWeakenedMember" xlink:label="loc_PNRLExchangeRateWeakenedMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_srtScenarioUnspecifiedDomain" xlink:to="loc_PNRLExchangeRateWeakenedMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GainsLossesOnExchangeDifferencesOnTranslationRecognisedInProfitOrLoss" xlink:label="loc_ifrs-fullGainsLossesOnExchangeDifferencesOnTranslationRecognisedInProfitOrLoss_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullGainsLossesOnExchangeDifferencesOnTranslationRecognisedInProfitOrLoss_50" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_GainsLossesOnExchangeDifferencesOnTranslationRecognisedInProfitOrLossForLongTerm" xlink:label="loc_PNRLGainsLossesOnExchangeDifferencesOnTranslationRecognisedInProfitOrLossForLongTerm_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLGainsLossesOnExchangeDifferencesOnTranslationRecognisedInProfitOrLossForLongTerm_50" xlink:type="arc" order="1" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfContractualObligationsDetails" xlink:title="00000061 - Disclosure - SCHEDULE OF CONTRACTUAL OBLIGATIONS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfContingentLiabilitiesInBusinessCombinationTable" xlink:label="loc_ifrs-fullDisclosureOfContingentLiabilitiesInBusinessCombinationTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfContingentLiabilitiesInBusinessCombinationTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ClassesOfContingentLiabilitiesAxis" xlink:label="loc_ifrs-fullClassesOfContingentLiabilitiesAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfContingentLiabilitiesInBusinessCombinationTable" xlink:to="loc_ifrs-fullClassesOfContingentLiabilitiesAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ContingentLiabilitiesMember" xlink:label="loc_ifrs-fullContingentLiabilitiesMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullClassesOfContingentLiabilitiesAxis" xlink:to="loc_ifrs-fullContingentLiabilitiesMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_ContingentLiabilitiesMember" xlink:label="loc_ifrs-fullContingentLiabilitiesMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullClassesOfContingentLiabilitiesAxis" xlink:to="loc_ifrs-fullContingentLiabilitiesMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LaterThanSixMonthsAndNotLaterThanOneYearMember" xlink:label="loc_ifrs-fullLaterThanSixMonthsAndNotLaterThanOneYearMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullContingentLiabilitiesMember" xlink:to="loc_ifrs-fullLaterThanSixMonthsAndNotLaterThanOneYearMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LaterThanOneYearAndNotLaterThanTwoYearsMember" xlink:label="loc_ifrs-fullLaterThanOneYearAndNotLaterThanTwoYearsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullContingentLiabilitiesMember" xlink:to="loc_ifrs-fullLaterThanOneYearAndNotLaterThanTwoYearsMember_10" xlink:type="arc" order="11" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LaterThanTwoYearsAndNotLaterThanFiveYearsMember" xlink:label="loc_ifrs-fullLaterThanTwoYearsAndNotLaterThanFiveYearsMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullContingentLiabilitiesMember" xlink:to="loc_ifrs-fullLaterThanTwoYearsAndNotLaterThanFiveYearsMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TradeAndOtherPayablesToTradeSuppliers" xlink:label="loc_ifrs-fullTradeAndOtherPayablesToTradeSuppliers_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullTradeAndOtherPayablesToTradeSuppliers_50" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PayablesForPurchaseOfNoncurrentAssets" xlink:label="loc_ifrs-fullPayablesForPurchaseOfNoncurrentAssets_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullPayablesForPurchaseOfNoncurrentAssets_50" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_LeaseLiabilities" xlink:label="loc_ifrs-fullLeaseLiabilities_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullLeaseLiabilities_50" xlink:type="arc" order="2" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TradeAndOtherPayablesToRelatedParties" xlink:label="loc_ifrs-fullTradeAndOtherPayablesToRelatedParties_50" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullTradeAndOtherPayablesToRelatedParties_50" xlink:type="arc" order="3" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfComponentsOfEquityDeficiencyLoansAndBorrowingOtherCurrentLiabilitiesNetOfCashDetails" xlink:title="00000062 - Disclosure - SCHEDULE OF COMPONENTS OF EQUITY DEFICIENCY, LOANS AND BORROWING, OTHER CURRENT LIABILITIES, NET OF CASH (Details)" />
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/ScheduleOfGeographicSegmentsDetails" xlink:title="00000063 - Disclosure - SCHEDULE OF GEOGRAPHIC SEGMENTS (Details)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfDisaggregationOfRevenueFromContractsWithCustomersTable" xlink:label="loc_ifrs-fullDisclosureOfDisaggregationOfRevenueFromContractsWithCustomersTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfDisaggregationOfRevenueFromContractsWithCustomersTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GeographicalAreasAxis" xlink:label="loc_ifrs-fullGeographicalAreasAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfDisaggregationOfRevenueFromContractsWithCustomersTable" xlink:to="loc_ifrs-fullGeographicalAreasAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GeographicalAreasMember" xlink:label="loc_ifrs-fullGeographicalAreasMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullGeographicalAreasAxis" xlink:to="loc_ifrs-fullGeographicalAreasMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GeographicalAreasMember" xlink:label="loc_ifrs-fullGeographicalAreasMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullGeographicalAreasAxis" xlink:to="loc_ifrs-fullGeographicalAreasMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_CanadaCountryMember" xlink:label="loc_PNRLCanadaCountryMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullGeographicalAreasMember" xlink:to="loc_PNRLCanadaCountryMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BarbadosCountryMember" xlink:label="loc_PNRLBarbadosCountryMember_20" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullGeographicalAreasMember" xlink:to="loc_PNRLBarbadosCountryMember_20" xlink:type="arc" order="21" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_BotswanaCountryMember" xlink:label="loc_PNRLBotswanaCountryMember_40" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullGeographicalAreasMember" xlink:to="loc_PNRLBotswanaCountryMember_40" xlink:type="arc" order="41" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CurrentAssets" xlink:label="loc_ifrs-fullCurrentAssets_90" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullCurrentAssets_90" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_PropertyPlantAndEquipment" xlink:label="loc_ifrs-fullPropertyPlantAndEquipment_90" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullPropertyPlantAndEquipment_90" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_TangibleExplorationAndEvaluationAssets" xlink:label="loc_ifrs-fullTangibleExplorationAndEvaluationAssets_90" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullTangibleExplorationAndEvaluationAssets_90" xlink:type="arc" order="2" />
    </link:definitionLink>
    <link:definitionLink xlink:type="extended" xlink:role="http://premiumnickelresources.com/role/SubsequentEventsDetailsNarrative" xlink:title="00000064 - Disclosure - SUBSEQUENT EVENTS (Details Narrative)">
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_IfrsStatementLineItems" xlink:label="loc_PNRLIfrsStatementLineItems" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_DisclosureOfNonadjustingEventsAfterReportingPeriodTable" xlink:label="loc_ifrs-fullDisclosureOfNonadjustingEventsAfterReportingPeriodTable" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/all" xbrldt:contextElement="segment" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_ifrs-fullDisclosureOfNonadjustingEventsAfterReportingPeriodTable" xlink:type="arc" order="10" xbrldt:closed="true" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NonadjustingEventsAfterReportingPeriodAxis" xlink:label="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/hypercube-dimension" xlink:from="loc_ifrs-fullDisclosureOfNonadjustingEventsAfterReportingPeriodTable" xlink:to="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NonadjustingEventsMember" xlink:label="loc_ifrs-fullNonadjustingEventsMember" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-domain" xlink:from="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" xlink:to="loc_ifrs-fullNonadjustingEventsMember" xlink:type="arc" order="20" />
      <link:loc xlink:type="locator" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NonadjustingEventsMember" xlink:label="loc_ifrs-fullNonadjustingEventsMember_10" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/dimension-default" xbrldt:contextElement="segment" xlink:from="loc_ifrs-fullNonadjustingEventsAfterReportingPeriodAxis" xlink:to="loc_ifrs-fullNonadjustingEventsMember_10" xlink:type="arc" order="30" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NonadjustingEventMember" xlink:label="loc_PNRLNonadjustingEventMember_0" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_ifrs-fullNonadjustingEventsMember" xlink:to="loc_PNRLNonadjustingEventMember_0" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_NumberOfWarrantsOutstanding" xlink:label="loc_PNRLNumberOfWarrantsOutstanding_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLNumberOfWarrantsOutstanding_30" xlink:type="arc" order="0" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_DescriptionForSubjectWarrants" xlink:label="loc_PNRLDescriptionForSubjectWarrants_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLDescriptionForSubjectWarrants_30" xlink:type="arc" order="1" />
      <link:loc xlink:type="locator" xlink:href="pnrl-20230331.xsd#PNRL_WarrantExercisePrice" xlink:label="loc_PNRLWarrantExercisePrice_30" />
      <link:definitionArc xlink:arcrole="http://xbrl.org/int/dim/arcrole/domain-member" xlink:from="loc_PNRLIfrsStatementLineItems" xlink:to="loc_PNRLWarrantExercisePrice_30" xlink:type="arc" order="2" />
    </link:definitionLink>
</link:linkbase>
